That’s a bit tricky. R/C by itself is relatively simple though; the problem is elsewhere.
For basic R/C, ou have the transmitter, and the vehicle has a receiver, and some things to take the signal sent from the transmitter to the receiver and make the vehicle do stuff. Those “things” are often servo motors that move some part of the vehicle, whether it be turning the front wheels of a car, moving the rudder of a boat/sub/plane, or actuating the carburetor of a small fuel-powered engine. Yes, some R/C vehicles use small 2-stroke engines, but even though they are called “gas powered”, they actually run on special fuel; trying to run them on regular gasoline will not only not work, but will probably do some damage. If you’re building a sub, odds are that you’ll be using electric motors; they are about the only way to move a sub without a snorkel, and electrics are FAR simpler than “gassers” anyways. Trust me, you really don’t want a gasser as your first.
Electric-powered vehicles often also have an Electronic Speed Control (ESC) that allows for controlling the speed of an electric motor with no moving parts; this a stark contrast from the old mechanical speed controls that used a servo.
That is the control end of things, and it is actually simpler than it would sound from the word count above. An electric car or boat will have one servo for steering, an ESC between the battery and the motor, and both of those will have a control wire plugged into the receiver. Four connections; that’s it!
Boats and subs have issues that transcend radio control though, and that will be your undoing. See, the motor itself cannot be in the water, but the props to move the sub/boat must be in the water. That means you have to have something along the driveshaft that seals water out while allowing free rotation of the shaft.
R/C subs have their own special requirements for diving, which you can read about here. But suffice it to say, despite having quite a few years with R/C cars under my belt, even I would be a little hesitant building my own sub. I would just get a hobby-grade kit (not one of those rinky-dink toys) and go from there.