As published in ScienceDaily (Nov. 15, 2007)
The colors of the sunset result from a phenomenon called scattering, says Steven Ackerman, professor of meteorology at UW-Madison. Molecules and small particles in the atmosphere change the direction of light rays, causing them to scatter.
Scattering affects the color of light coming from the sky, but the details are determined by the wavelength of the light and the size of the particle. The short-wavelength blue and violet are scattered by molecules in the air much more than other colors of the spectrum. This is why blue and violet light reaches our eyes from all directions on a clear day. But because we can’t see violet very well, the sky appears blue.
Scattering also explains the colors of the sunrise and sunset, Ackerman says.
“Because the sun is low on the horizon, sunlight passes through more air at sunset and sunrise than during the day, when the sun is higher in the sky. More atmosphere means more molecules to scatter the violet and blue light away from your eyes. If the path is long enough, all of the blue and violet light scatters out of your line of sight. The other colors continue on their way to your eyes. This is why sunsets are often yellow, orange, and red.”
And because red has the longest wavelength of any visible light, the sun is red when it’s on the horizon, where its extremely long path through the atmosphere blocks all other colors.
Sunrise colors are typically less brilliant and less intense than sunset colors, since there are generally fewer particles and aerosols in the morning air than in the evening air. Nighttime air is usually cooler and less windy, which allows dust and soot particles to settle out of the atmosphere, reducing the amount of scattering. The reduced scattering correspondingly reduces the amount of red and orange scattered light at sunrise. Sunrise color intensities can however exceed sunset’s intensities when there are nighttime fires, volcanic eruptions or emissions, or dust storms to the east of the viewer.